Copolymerization of olefins

ABSTRACT

Ethylene and/or propylene, and α-olefins may be copolymerized by contacting then with certain iron or cobalt complexes of selected 2,6-pyridinecarboxaldehydebis(imines) and 2,6-diacylpyridinebis(imines). The polymers produced, some of which are novel, are useful as molding resins.

This application is a divisional of application Ser. No. 10/251,041, filed Sep. 20, 2002, which is a continuation of application Ser. No. 09/946,170, filed Sep. 4, 2001, now abandoned, which is a continuation of application Ser. No. 09/317,563, filed May 24, 1999, now abandoned, which claims benefit of Provisional Application No. 60/087,152, filed May 29, 1998.

FIELD OF THE INVENTION

Selected iron and cobalt complexes of 2,6-pyridinecarboxaldehydebis(imines) and 2,6-diacylpyridinebis(imines) are catalysts for the copolymerization of ethylene and/or propylene and α-olefins. Novel polymers may be produced.

FIELD OF THE INVENTION

Copolymers of ethylene and/or propylene and α-olefins, such as linear low density polyethylene (LLDPE) are important items of commerce, millions of tons being produced annually. These polymers are used in a myriad of ways, such as for fiber, films, molding resins, etc. In most cases, ethylene and α-olefins are copolymerized using a catalyst, often a transition metal compound or complex. These catalysts may vary in cost per unit weight of polymer produced, the structure of the polymer produced, the possible need to remove the catalyst from the polymer, the toxicity of the catalyst, etc. Due to the commercial importance of copolymerizing ethylene, new polymerization catalysts are constantly being sought.

B. L. Small, et al., J. Am. Chem. Soc., vol. 120, p. 4049-4050 (1998), and G. J. P. Britovsek, et al., J. Chem. Soc., Chem. Commun., p. 849-850 (1998) report the polymerization of ethylene using catalysts containing Fe or Co complexes of 2,6-pyridinecarboxaldehydebis(imines) and 2,6-diacylpyridinebis(imines). Copolymerization of α-olefins and ethylene are not reported.

SUMMARY OF THE INVENTION

This invention concerns a first polymerization process, comprising, contacting, at a temperature of about −100° C. to about +200° C., a compound of the formula

with one or both of ethylene and propylene, and an olefin of the formula H₂C═CHR²¹ and:

-   -   (a) a first compound W, which is a neutral Lewis acid capable of         abstracting X an alkyl group or a hydride group from M to form         WX⁻, (WR²⁰)⁻ or WH⁻ and which is also capable of transferring an         alkyl group or a hydride to M, provided that WX⁻ is a weakly         coordinating anion; or     -   (b) a combination of second compound which is capable of         transferring an alkyl or hydride group to M and a third compound         which is a neutral Lewis acid which is capable of abstracting         XC, a hydride or an alkyl group from M to form a weakly         coordinating anion;     -   wherein:     -   M is Co or Fe;     -   each X is an anion;     -   n is 1, 2 or 3 so that the total number of negative charges on         said anion or anions is equal to the oxidation state of a Fe or         Co atom present in (II);     -   R¹, R² and R³ are each independently hydrogen, hydrocarbyl,         substituted hydrocarbyl, or an inert functional group;     -   R⁴ and R⁵ are each independently hydrogen, hydrocarbyl, an inert         functional group or substituted hydrocarbyl;     -   R⁶ and R⁷ are aryl or substituted aryl;     -   R²⁰ is alkyl; and     -   R²¹ is alkyl.

This invention also concerns a second polymerization process, comprising contacting, at a temperature of about −100° C. to about +200° C., a Co[II], Co[III], Fe[II] or Fe[III] complex of a tridentate ligand of the formula

with one or both of ethylene and propylene, and an olefin of the formula H₂C═CHR²¹ wherein:

-   -   R¹, R² and R³ are each independently hydrogen, hydrocarbyl,         substituted hydrocarbyl, or an inert functional group;     -   R⁴ and R⁵ are each independently hydrogen, hydrocarbyl, an inert         functional group or substituted hydrocarbyl; and

R⁶ and R⁷ are aryl or substituted aryl;

-   -   R²¹ is alkyl;     -   and provided that a Co[II], Co[III], Fe[II] or Fe[III] atom also         has bonded to it an empty coordination site or a ligand that may         be displaced by said ethylene, and a ligand that may add to said         ethylene.

This invention also concerns a third polymerization process, comprising, contacting, at a temperature of about −100° C. to about +200° C., one or both of ethylene and propylene, an olefin of the formula H₂C═CHR²¹, and a compound of the formula

-   -   wherein:         -   M is Co or Fe;         -   R¹, R² and R³ are each independently hydrogen, hydrocarbyl,             substituted hydrocarbyl, or an inert functional group;         -   R⁴ and R⁵ are each independently hydrogen, hydrocarbyl, an             inert functional group or substituted hydrocarbyl; and         -   R⁶ and R⁷ are aryl or substituted aryl;         -   R²¹ is alkyl;         -   T¹ is hydride or alkyl or any other anionic ligand into             which ethylene or an α-olefin can insert;         -   Y is a neutral ligand capable of being displaced by ethylene             or a vacant coordination site;         -   Q is a relatively non-coordinating anion;         -   P is a divalent polyolefin group; and     -   T² is an end group.

DETAILS OF THE INVENTION

Herein, certain terms are used. Some of them are:

-   -   A “hydrocarbyl group” is a univalent group containing only         carbon and hydrogen. If not otherwise stated, it is preferred         that hydrocarbyl groups herein contain 1 to about 30 carbon         atoms.     -   By “substituted hydrocarbyl” herein is meant a hydrocarbyl group         which contains one or more substituent groups which are inert         under the process conditions to which the compound containing         these groups is subjected. The substituent groups also do not         substantially interfere with the process. If not otherwise         stated, it is preferred that substituted hydrocarbyl groups         herein contain 1 to about 30 carbon atoms. Included in the         meaning of “substituted” are heteroaromatic rings. All of the         hydrogen atoms may be substituted for, as in trifluoromethyl.     -   By “(inert) functional group” herein is meant a group other than         hydrocarbyl or substituted hydrocarbyl which is inert under the         process conditions to which the compound containing the group is         subjected. The functional groups also do not substantially         interfere with any process described herein that the compound in         which they are present may take part in. Examples of functional         groups include halo (fluoro, chloro, bromo and iodo), ether such         as —OR¹⁸ wherein R¹⁸ is hydrocarbyl or substituted hydrocarbyl.         In cases in which the functional group may be near a cobalt or         iron atom, such as R⁴ and R⁵, the functional group should not         coordinate to the metal atom more strongly than the groups in         compounds containing R⁴ and R⁵, which are shown as coordinating         to the metal atom, that is they should not displace the desired         coordinating group.     -   By an “alkyl aluminum compound” is meant a compound in which at         least one alkyl group is bound to an aluminum atom. Other groups         such as alkoxide, hydride, and halogen may also be bound to         aluminum atoms in the compound.     -   By “neutral Lewis base” is meant a compound, which is not an         ion, which can act as a Lewis base. Examples of such compounds         include ethers, amines, sulfides, and organic nitrites.     -   By “cationic Lewis acid” is meant a cation which can act as a         Lewis acid. Examples of such cations are sodium and silver         cations.     -   By relatively noncoordinating (or weakly coordinating) anions         are meant those anions as are generally referred to in the art         in this manner, and the coordinating ability of such anions is         known and has been discussed in the literature, see for         instance W. Beck., et al., Chem. Rev., vol. 88 p. 1405-1421         (1988), and S. H. Stares, Chem. Rev., vol. 93, p. 927-942         (1993), both of which are hereby included by reference. Among         such anions are those formed from the aluminum compounds in the         immediately preceding paragraph and X⁻, including R⁹ ₃AlX⁻, R⁹         ₂AlClX⁻, R⁹AlCl₂X⁻, and “R⁹AlOX⁻”, wherein R⁹ is alkyl. Other         useful noncoordinating anions include BAF⁻         {BAF=tetrakis[3,5-bis(trifluoromethyl)phenyl]borate}, SbF₆ ⁻,         PF₆ ⁻, and BF₄ ⁻, trifluoromethanesulfonate, p-toluenesulfonate,         (R_(f)SO₂)₂N⁻, and (C₆F₅)₄B⁻.     -   By an empty coordination site is meant a potential coordination         site that does not have a ligand bound to it. Thus if an         ethylene molecule is in the proximity of the empty coordination         site, the ethylene or other olefin molecule may coordinate to         the metal atom.     -   By a “divalent polyolefin group” is meant a group —Z— which         contains one or more ethylene and/or α-olefin repeat units.     -   By a ligand that may add to ethylene, propylene, or an α-olefin         is meant a ligand coordinated to a metal atom into which an         ethylene molecule (or a coordinated ethylene molecule) may         insert to start or continue a polymerization. For instance, this         may take the form of the reaction (wherein L is a ligand):         Note the similarity of the structure on the left-hand side of         this equation to compound (IX) (see below).

Compounds useful as ligands herein in iron and cobalt complexes are diimines of 2,6-pyridinedicarboxaldehyde or 2,6-diacylpyridines of the general formula

wherein R¹, R² and R³ are each independently hydrogen, hydrocarbyl, substituted hydrocarbyl, or an inert functional group, R⁴ and R⁵ are each independently hydrogen, hydrocarbyl, an inert functional group or substituted hydrocarbyl, and R⁶ and R⁷ are aryl or substituted aryl.

(IV) may be made by the reaction of a compound of the formula

with a compound of the formula H₂NR⁶ or H₂NR⁷, wherein R¹, R² and R³ are each independently hydrogen, hydrocarbyl, substituted hydrocarbyl, or an inert functional group, R⁴ and R⁵ are each independently hydrogen, hydrocarbyl or substituted hydrocarbyl, R⁴ and R⁵ are each hydrocarbyl or substituted hydrocarbyl, and R⁶ and R⁷ are aryl or substituted aryl. These reactions are often catalyzed by carboxylic acids, such as formic acid.

Preferred compounds of formula (IV) and compounds in which (IV) is a ligand are those of compound (III) [note

that (III) is a subset of (IV)], whether present in compounds such as (I), (II), (IV), (VII), (IX) and (XII). In (III), and hence in (I), (II), (IV) (VII), (IX) and (XII) that match the formula of (III), it is preferred that:

-   -   R¹, R² and R³ are hydrogen; and/or     -   R¹ and R³ are hydrogen and R² is trifluoromethyl; and/or     -   R⁹, R¹⁰, R¹¹, R¹⁴, R¹⁵ and R¹⁶ is each independently halogen,         alkyl containing 1 to 6 carbon atoms, or hydrogen, and it is         more preferred that each of these is hydrogen; and/or     -   R¹⁰ and R¹⁵ are methyl; and/or     -   R⁶ and R¹³ is each independently halogen, phenyl or alkyl         containing 1 to 6 carbon atoms, and it is especially preferred         that each R⁸ and R¹³ is alkyl containing 1-6 carbon atoms and is         more preferred that R⁸ and R¹³ are methyl; and/or     -   R¹² and R¹⁷ is each independently halogen, phenyl, hydrogen, or         alkyl containing 1 to 6 carbon atoms, and it is especially         preferred that each R¹² and R¹⁷ is alkyl containing 1-6 carbon         atoms, and it is more preferred that R¹² and R¹⁷ are methyl;         and/or     -   R⁴ and R⁵ are each independently halogen, thioalkyl, hydrogen or         alkyl containing 1 to 6 carbon atoms, and it is especially         preferred that R⁴ and R⁵ are each independently hydrogen or         methyl; and/or     -   R⁸, R¹⁰, R¹³, R¹⁵ and R¹⁷ are hydrogen, and R⁹, R¹¹, R¹⁴ and R¹⁶         are hydrocarbyl or substituted hydrocarbyl.

Also in (III), and hence in (I), (II), (IV) (VII), (IX) and (XII) that match the formula of (III), it is preferred that:

-   -   R⁸ and R¹³ are each independently hydrogen, hydrocarbyl,         substituted hydrocarbyl or an inert functional group;     -   R⁹, R¹⁰, R¹¹, R¹⁴, R¹⁵ and R¹⁶ are each independently hydrogen,         hydrocarbyl, substituted hydrocarbyl or an inert functional         group;     -   R¹² and R¹⁷ are each independently hydrogen, hydrocarbyl,         substituted hydrocarbyl or an inert functional group;     -   and provided that any two of R⁸, R⁹, R¹⁰, R¹¹, R¹², R¹³, R¹⁴,         R¹², R¹³ and R¹⁷ that are vicinal to one another, taken together         may form a ring.

Specific preferred compounds (III) [and also in (I), (II), (IV), (VII), (IX) and (XII)] are:

-   -   R¹, R², R³, R⁹, R¹¹, R¹⁴ and R¹⁶ are hydrogen, and R⁴, R⁵, R⁸,         R¹⁰, R¹², R¹³, R¹⁵ and R¹⁷ are methyl;     -   R¹, R², R³, R⁹, R¹⁰, R¹¹, R¹⁴, R¹⁵ and R¹⁶ are hydrogen, R⁸ and         R¹³ are chloro, and R⁴, R⁵, R¹² and R¹⁷ are methyl;     -   R¹, R², R³, R⁹, R¹⁰, R¹¹, R¹², R¹⁴, R¹⁵, R¹⁶ and R¹⁷ are         hydrogen, R⁴ and R⁵ are methyl, and R⁸ and R¹³ are phenyl;     -   R¹, R², R³, R⁴, R⁵, R⁹, R¹⁰, R¹¹, R¹⁴, R¹⁵, and R¹⁶ are         hydrogen, and R⁸, R¹², R¹³ and R¹⁷ are i-propyl; and     -   R¹, R², R³, R⁴R⁵, R¹⁰, R⁸, R¹⁰, R¹³, R¹⁵ R¹⁷ are hydrogen, and         R⁹, R¹¹, R¹⁴ and R¹⁵ are trifluoromethyl.

In the polymerization processes described herein, it can be seen from the results that it is preferred that there be at least some steric crowding caused by the tridentate ligand about the Co or Fe atom. Therefore, it is preferred that groups close to the metal atom be relatively large. It is relatively simple to control steric crowding if (III) is the tridentate ligand, since control of steric crowding can be achieved simply by controlling the size of R⁸, R¹², R¹³ and R⁶. These groups may also be part of fused ring systems, such as 9-anthracenyl.

In the first polymerization process it is preferred that X is chloride, bromide and tetrafluoroborate. It is also preferred that M is Fe[II] or Fe[III].

In the first polymerization process described herein an iron or cobalt complex (II) is contacted with ethylene, an α-olefin and a neutral Lewis acid W capable of abstracting X, hydride or alkyl from (II) to form a weakly coordinating anion, and must alkylate or be capable of adding a hydride ion to the metal atom, or an additional alkylating agent or an agent capable of adding a hydride anion to the metal atom must be present. The neutral Lewis acid is originally uncharged (i.e., not ionic). Suitable neutral Lewis acids include SbF₅, Ar₃B (wherein Ar is aryl), and BF₃. Suitable cationic Lewis acids or Bronsted acids include NaBAF, silver trifluoromethanesulfonate, HBF₄, or [C₆H₅N(CH₃)2]⁺[B(C₆F₅)₄]⁻. In those instances in which (II) (and similar catalysts which require the presence of a neutral Lewis acid or a cationic Lewis or Bronsted acid), does not contain an alkyl or hydride group already bonded to the metal atom, the neutral Lewis acid or a cationic Lewis or Bronsted acid also alkylates or adds a hydride to the metal or a separate alkylating or hydriding agent is present, i.e., causes an alkyl group or hydride to become bonded to the metal atom.

It is preferred that R²⁰ contains 1 to 4 carbon atoms, and more preferred that R²⁰ is methyl or ethyl.

For instance, alkyl aluminum compounds (see next paragraph) may alkylate (II). However, not all alkyl aluminum compounds may be strong enough Lewis acids to abstract X or an alkyl group from the metal atom. In that case a separate Lewis acid strong enough to do the abstraction must be present.

A preferred neutral Lewis acid, which can alkylate the metal, is a selected alkyl aluminum compound, such as R¹⁹ ₃Al, R¹⁹AlCl₂, R¹⁹ ₂AlCl, and “R¹⁹AlO” (alkylaluminoxanes), wherein R¹⁹ is alkyl containing 1 to 25 carbon atoms, preferably 1 to 4 carbon atoms. Suitable alkyl aluminum compounds include methylaluminoxane (which is an oligomer with the general formula [MeAlO]_(n)), (C₂H₅)₂AlCl, C₂H₅AlC₂, and [(CH₃)₂CHCH₂]₃Al.

Metal hydrides such as NaBH₄ may be used to bond hydride groups to the metal M.

In the second polymerization process described herein a cobalt or iron complex of (I) is either added to the polymerization process or formed in situ in the process. In fact, more than one such complex may be formed during the course of the process, for instance formation of an initial complex and then reaction of that complex to form a living ended polymer containing such a complex.

Examples of such complexes which may be formed initially in situ include

wherein R¹ through R⁷, and M are as defined above, T¹ is hydride or alkyl or any other anionic ligand into which ethylene or an α-olefin can insert, Y is a neutral ligand capable of being displaced by ethylene, propylene or an α-olefin, or a vacant coordination site, the “parallel lines” are an ethylene molecule coordinated to the metal, and Q is a relatively non-coordinating anion. Complexes may be added directly to the process or formed in situ. For instance, (VII) may be formed by the reaction of (II) with a neutral Lewis acid such as an alkyl aluminum compound. Another method of forming such a complex in situ is adding a suitable iron or cobalt compound such as iron [II] acetylacetonate, (I) and an alkyl aluminum compound. Other metal salts in which anions similar to acetylacetonate are present, and which may be removed by reaction with the Lewis or Bronsted acid. For instance metal halides and carboxylates (such as acetates) may be used, particularly if they are slightly soluble in the process medium. It is preferred that these precursor metal salts be at least somewhat soluble in the process medium.

After the polymerization has started, the complex may be in a form such as

wherein R¹ through R⁷, M, and Q are as defined above, and P is a divalent polymeric groups containing repeat units derived from ethylene and/or propylene and/or an α-olefin, and T² is an end group, for example the groups listed for T¹ above. Those skilled in the art will note that (IX) is in essence a polymer containing a so-called living end. It is preferred that M be in +2 oxidation state in (VII), (VIII) and (IX). Compounds such as (VII), (IX) and (XII) may or may not be stable away from an environment similar to that of the polymerization process, but they may be detected by NMR spectroscopy, particularly one or both of ¹H and ¹³C NMR, and particularly at lower temperatures. Such techniques, especially for polymerization “intermediates” of these types are known, see for instance World Patent Application 96/23010, especially Examples 197-203, which is hereby included by reference.

(VII), (IX) and (XII) may also be used, in the absence of any “co-catalysts” or “activators” to polymerize ethylene in a third polymerization process. Except for the ingredients in the process, the process conditions for the third process, such as temperature, pressure, polymerization medium, etc., may be the same as for the first and second polymerization processes, and preferred conditions for those processes are also preferred for the third polymerization process.

In all the polymerization processes herein, the temperature at which the ethylene copolymerization is carried out is about −100° C. to about +200° C., preferably about −60° C. to about 150° C., more preferably about −50° C. to about 100° C.

For copolymerization one or more α-olefins of the formula H₂C═CHR²¹ may be used. It is preferred that R²¹ have 1 to 18 carbon atoms, more preferably 2 to 8 carbon atoms, and/or that R²¹ be n-alkyl. Since ethylene is polymerized considerably faster than propylene and most α-olefins by these catalysts, in order to obtain substantial incorporation of the α-olefin(s), the concentration of ethylene in the polymerization should preferably be relatively low compared to the concentration of the propylene and α-olefin(s). This will most often entail using ethylene at a low partial pressure, preferably less than 1.0 MPa, more preferably less than 500 kPa, and especially preferably less than 300 kPa (all these ethylene partial pressures are absolute partial pressures). If the α-olefin is a gas its partial pressure should preferably be relatively high. If the α-olefin is used in the liquid phase, its liquid concentration should preferably be relatively high.

NMR analysis of the product copolymers shows that the end groups are both saturated and unsaturated (olefinic), although saturated end groups usually outnumber unsaturated end groups. It is suspected that saturated end groups may arise through initiation and chain transfer involving alkyl aluminum compounds present in the polymerization. Unsaturated end groups are believed to arise though a β-hydride elimination-type mechanism. A small proportion of the olefinic ends appear to be internal olefins, but the majority of the olefinic ends are usually α-olefins (terminal olefins).

It is preferred that the product copolymer have at least 0.5 mole percent (total), more preferably 0.75 mole percent (total), especially preferably 1 mole percent (total), and highly preferably at least about 2 mole percent (total) of α-olefin(s) incorporated into the product copolymer. When 1-hexene is a comonomer the percent incorporated versus short chain branches, assuming all such branches are butyl, is shown in the following Table. Mole Percent n-Butyl Branches 1-Hexene per 1000 C Atoms 0.5 2.5 0.75 3.7 1.0 4.9 2.0 9.6 10.0 41.7

In copolymers of ethylene and H₂C═CHR²¹ produced herein the polymer will contain —R²¹ branches and methyl branches. The total amount of H₂C═CHR²¹ is taken as the total of the —R²¹ branches in the polymer, calculated according to a suitable formula, for example branches per 1000 carbon atoms or mole percent of H₂C═CHR²¹ incorporated. It is believed that the methyl branches in the copolymer are associated with the end groups (but are not the end groups themselves). for example, end groups associated with methyl branches are ˜˜˜˜˜CH₂CH(CH₃)CH₂CH₂CH₃ and ˜˜˜˜˜CH₂CH(CH₃)CH₂CH₂CH₂CH₃ are the methyl branch associated groups for 1-pentene and 1-hexene respectively (and similar structures for higher and lower homologs), wherein “˜˜˜˜” is the remainder of the polymer chain. Such groups are detectable by ¹³C-NMR because methyl branches near the chain ends are somewhat different than methyl branches further in the interior of the polymer chain, see for instance the Examples herein. Note that the group beyond the methine carbon atom (towards the chain end) is actually —R²¹ In other words the methyl branch is attached to the same carbon atom as an —R²¹ group. Not all polymer chains have such chain ends, but usually at least some of them are present in these copolymers.

A preferred monomer combination is ethylene and one or more olefins of the formula H₂C═CHR²¹.

During the polymerization process often some or most of the olefin comonomer H₂C═CHR²¹ will be unused in the polymerization. Testing of this unused comonomer at the end of the polymerization process shows that it is usually essentially unaltered (not isomerized), so it may be recovered and recycled into the polymerization, if desired. This recycling may take place without purification, or the comonomer may be purified being recycled to the polymerization, as by distillation.

The polymerization processes herein may be run in the presence of various liquids, particularly aprotic organic liquids. The catalyst system, ethylene, propylene, α-olefin, and polyolefin may be soluble or insoluble in these liquids, but obviously these liquids should not prevent the polymerization from occurring. Suitable liquids include alkanes, cycloalkanes, selected halogenated hydrocarbons, and aromatic hydrocarbons. Specific useful solvents include hexane, toluene and benzene.

The copolymerizations herein may also initially be carried out in the solid state [assuming (II), (III) (IV) or (VII) is a solid] by, for instance, supporting (II), (III) (IV) or (VII) on a substrate such as silica or alumina or an organic substrate such as a polymer, activating it with the Lewis (such as W, for instance an alkylaluminum compound) or Bronsted acid and exposing it to an olefin. The support may also be able to take the place of the Lewis or Bronsted acid, for instance an acidic clay such as montmorillonite. Another method of making a supported catalyst is to start a polymerization or at least make an iron or cobalt complex of another olefin or oligomer of an olefin such as 1-hexene on a support such as silica or alumina. These “heterogeneous” catalysts may be used to catalyze polymerization in the gas phase or the liquid phase. By gas phase is meant that the monomers are transported to contact with the catalyst particle while they are in the gas phase.

Hydrogen may be used as a chain transfer agent in all of the polymerization processes described herein.

In all of the polymerization processes described herein oligomers and copolymers of ethylene and/or propylene are made. They may range in molecular weight from oligomers, to lower molecular weight oils and waxes, to higher molecular weight polyolefins. One preferred product is a polymer with a degree of polymerization (DP) of about 10 or more, preferably about 40 or more. By “DP” is meant the average number of repeat (monomer) units in a polymer molecule.

In the Examples, the pressures given are gauge pressures. Methods of NMR analysis for polymer branching, and the notation used herein to describe the branching as determined by ¹³C NMR, are found in U.S. Pat. No. 5,880,241 (equivalent of World Patent Application 96/23010), which is hereby included by reference. Syntheses of the diimine ligands and their Co and Fe complexes are found in B. L. Small, et al., J. Am. Chem. Soc., vol. 120, p. 4049-4050 (1998), and G. J. P. Britovsek, et al., J. Chem. Soc., Chem. Commun., p. 849-850 (1998), which are both hereby included by reference. The following abbreviations and terms are used:

-   -   DSC—differential scanning calorimetry     -   GC—gas chromatography     -   GPC—gel permeation chromatography     -   HOF—heat of fusion     -   IBAO-0.65—isobutylaluminoxane produced by the reaction of         triisobutylaluminum with 0.65 equivalents of water     -   MMAO-3A—methylaluminoxane containing some isobutyl groups     -   Mn—number average molecular weight     -   MeOH—methanol     -   PMAO—polymethylaluminoxane     -   PMAO-IP—polymethylaluminoxane (Akzo, 12.8 weight percent         aluminum in toluene)     -   PDI—weight average molecular weight divided by number average         molecular weight (Mn)     -   TCB—1,2,4-trichlorobenzene

Tm—melting point

EXAMPLE 1

In a drybox under a nitrogen atmosphere, (XIII) (8 mg, 0.015 mmol) was weighed into a Schienk flask and slurried in 20 ml anhydrous toluene. 1-Octene (3 ml, dried by distillation from sodium) was added and the Schlenk flask sealed and removed from the drybox. The flask was flushed well with ethylene and pressurized to 35 kPa. PMAO-IP (0.8 ml) was added and the solution turned orange and warmed. After 30 min the reaction was quenched by addition of MeOH. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=2.7 g white polymer. DSC (l⁰° C./min, N₂); Tm=123.2° C., shoulder on peak at 100° C. GPC (120° C., TCB); Mn=1500, PDI=5.6. The lowered (from pure polyethylene) melting point shows incorporation of comonomer.

EXAMPLE 2

In a drybox under a nitrogen atmosphere, (XIII) (7.5 mg, 0.014 mmol) was weighed into a Schlenk flask and slurried in 10 ml anhydrous toluene. 1-Hexene (3 ml, dried by distillation from sodium) was added and the Schlenk flask sealed and removed from the drybox. The flask was flushed well with ethylene and pressurized to 35 kPa. PMAO-IP (0.8 ml) was added and the solution turned green and warmed. After 30 min the reaction was quenched by addition of MeOH. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=6.0 g white polymer. DSC (10° C./min, N₂); Tm=126.3° C., shoulder on low temperature side of peak. GPC (120° C., TCB); Mn=2420, PDI=8.0. ¹³C-NMR analysis indicated a total of 2.5 mol % 1-hexene incorporation. The branching was >75% butyl branches (1,2 or 2,1 incorporation). Amyl and methyl branches were also observed at low levels. No ethyl or propyl branches were observed.

EXAMPLE 3

In a drybox under a nitrogen atmosphere, (XIII) (2.0 mg) was weighed into a flask and slurried in 35 ml 1-hexene (Aldrich, 99+%, filtered through Al₂O₃ and stored over activated molecular sieves). The flask was stoppered and removed from the drybox. PMAO-IP (1.0 ml) was added to ml anhydrous toluene and placed in a vial and removed from the drybox. The 1-hexene slurry was placed in a 100 ml Parr® stirred autoclave under an atmosphere of nitrogen. Stirring was started and the reactor heated to 50° C. The PMAO solution was then added to the reactor with 140 kPa ethylene. After 10 min the reaction was quenched by addition of MeOH. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=7.8 g white polymer. DSC (10° C./min., N₂); Tm=102.0° C. with a minor peak at 112.0° C. GPC (120° C., trichlorobenzene); Mn=2534, PDI=2.3. ¹³C-NMR analysis (5 weight percent in TCB, 120° C.) indicated a total of 3.9 mol % 1-hexene incorporation. Of this most resulted in butyl branches (1,2 or 2,1 incorporation). Trace amounts of amyl and methyl branches were also observed. No ethyl or propyl branches were observed. The observed NMR is given below together with the assignments. The assignments of D, E and F are shown in the structure below, with “P” representing the rest of the polymer chain.

Frequency PPM Height Assignment 3816.348 37.946 32.9 MB₄ 3716.490 36.954 2.0 3498.618 34.787 4.3 3455.364 34.357 67.6 αγ⁺B 3415.848 33.964 36.4 4B₄ 3320.796 33.019 2.7 D 3224.143 32.058 10.8 3B₆₊, 3EOC 3052.729 30.354 75.6 γγ⁺B 3004.669 29.876 1417.0 γ⁺γ⁺B 2953.405 29.366 50.9 3B₄ 2728.058 27.125 67.0 βγ⁺B 2340.374 23.271 37.6 2B₄ 2290.178 22.772 10.1 2B₅₊, 2EOC 1994.877 19.835 2.3 E 1412.818 14.048 40.1 1B₄₊, 1EOC

EXAMPLE 4

In a drybox under a nitrogen atmosphere, (XIII) (6.1 mg, 0.011 mmol) was weighed into a Schlenk flask and slurried in 10 ml anhydrous toluene. 1-Hexene (5 ml, dried by distillation from sodium) and anhydrous toluene (15 ml) were added and the Schlenk flask sealed and removed from the drybox. The flask was cooled to 0° C. and then flushed well with ethylene and pressurized to 35 kPa. PMAO-IP (0.9 ml) was added and the solution turned green and warmed. After 30 min the reaction was quenched by addition of MeOH. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=2.7 g white polymer. DSC (10° C./min, N₂); Tm=127.6° C., shoulder on low temperature side of peak. GPC (120° C., trichlorobenzene); Mn=2120, PDI=19.1. ¹³C-NMR analysis indicated a total of 1.2 mol % 1-hexene incorporation. Only methyl and butyl branches were observed (1,2 or 2,1 incorporation).

COMPARATIVE EXAMPLE A

In a drybox under a nitrogen atmosphere, (XIII) (7.5 mg, 0.014 mmol) was weighed into a Schlenk flask and slurried in 10 ml anhydrous toluene. Anhydrous toluene (30 ml) was added and the Schlenk sealed and removed from the drybox. The flask was cooled to 0° C. and then flushed well with ethylene and pressurized to 35 kPa. PMAO-IP (0.9 ml) was added and the solution turned orange and warmed. After 30 min the reaction was quenched by addition of MeOH. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=1.9 g white polymer. DSC (10° C./min, N2); Tm=132.7° C. GPC (120° C., trichlorobenzene); Mn=2900, PDI=19.1.

EXAMPLE 5

In a drybox under nitrogen, (XIII) (1.8 mg) was placed in 1-hexene (25 ml, Aldrich 99+%, filtered through activated Al₂O₃ and stored over activated molecular sieves) in a Hoke cylinder and sealed. PMAO-IP (0.9 ml) was placed in 2 ml anhydrous toluene in a vial and sealed. The containers were removed from the drybox. The 1-hexene slurry was placed in a Parr® stirred autoclave. Ethylene (70 kPa) was added, stirring started and the mixture heated to 75° C. The PMAO-IP solution was added to the reactor with an additional 160 kPa ethylene. After 81 min the reaction was quenched by addition of MeOH. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=1.61 g white polymer. DSC (10° C./min., N2); Tm(2^(nd) heat)=115.5° C. GPC (135° C., TCB); Mn=1090, PDI=1.8.

¹³C-NMR analysis indicated a total of 1.4 mol % 1-hexene incorporation. The observed number of short chain branches per 1000 CH₂ groups were methyl 1.9, butyl 7.1 and amyl 1.4.

EXAMPLE 6

In a drybox under nitrogen, (XIV) (6.0 mg) was placed in a Schlenk flask and anhydrous toluene (5 ml) and 1-hexene (10 ml, Aldrich 99+%, filtered through activated Al₂O₃ and stored over activated molecular sieves) added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and PMAO-IP (0.9 ml) added. After 30 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=2.43 g white polymer. DSC (10° C./min., N₂); Tm(2^(nd) heat)=123.1° C., 109.2° C. (broad). GPC (135° C., TCB); Mn=1620, PDI=8.4. ¹³C-NMR analysis indicated a total of 2.1 mol % 1-hexene incorporation. The observed number of short chain branches per 1000 CH₂ groups were methyl 0.8, butyl 10.5 and amyl 1.5.

EXAMPLE 7

In a drybox under nitrogen, (XIII) (3.0 mg) was placed in a Schlenk flask and anhydrous toluene (5 ml) and 1-hexene (10 ml, Aldrich 99+%, filtered through activated Al₂O₃ and stored over activated molecular sieves) added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and MMAO-3A (0.45 ml, Akzo, 6.42 wt % Al in heptane) added. After 30 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=1.1 g white polymer. DSC (10° C./min., N₂); Tm(2^(nd) heat)=121.0° C., 80° C. (broad). GPC (135° C., TCB); Mn=1507, PDI=6.6. ¹³C-NMR analysis indicated a total of 6.4 mol % 1-hexene incorporation. The observed number of short chain branches per 1000 CH₂ groups was methyl 1.9 butyl 30.5 and amyl 0.5. In addition, isobutyl ends are observed on the polymer (from the MMAO activator), and in this instance the isobutyl ends are not included in the methyl branch total.

EXAMPLE 8

In a drybox under nitrogen, (XIII) (6.3 mg) was placed in a Schlenk flask and anhydrous toluene (5 ml) and 1-heptene (10 ml, distilled from Na) added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and PMAO-IP (0.9 ml) added. After 30 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=0.87 g white polymer. DSC (10° C./min., N₂); Tm(2^(nd) heat)=122.3° C. GPC (135° C., TCB); Mn=2680, PDI=5.9. ¹³C-NMR analysis (10 weight percent in TCB, 120° C.) indicated a total of 5.3 mol % 1-heptene incorporation. The observed number of short chain branches per 1000 CH₂ groups were methyl 2.3, and amyl 24.6. The observed NMR is given below together with the assignments. The assignments of D, E and F are shown in the structure below, with “P” representing the rest of the polymer chain.

Frequency PPM Height Assignment 3857.777 38.358 8.4 3820.931 37.992 58.6 MB₄₊ 3750.443 37.291 7.4 F 3622.817 36.022 3.5 3502.133 34.822 10.8 3455.675 34.360 132.6 αB₃₊ 3398.004 33.787 4.6 3323.778 33.049 4.9 D 3274.116 32.555 81.1 3B₅ 3223.386 32.051 18.3 3B₆₊, 3EOC 3142.218 31.243 7.9 3080.808 30.633 30.3 3051.438 30.341 108.0 γγ⁺B 3003.378 29.863 2327.2 γ⁺γB 2961.192 29.444 43.1 2776.429 27.606 8.3 2727.835 27.123 106.6 βγ⁺B 2688.319 26.730 74.4 4B₅ 2449.621 24.357 4.8 2289.422 22.764 98.3 2B₅₊, 2EOC 1994.654 19.833 4.8 E 1408.323 14.003 95.4 1B_(4+, 1EOC)

COMPARATIVE EXAMPLE B

In a drybox under nitrogen, (XIII) (6.3 mg) was placed in a Schlenk flask and anhydrous toluene (15 ml added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and PMAO-IP (0.9 ml) added. After 30 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=1.1 g white polymer. DSC (10° C./min., N₂); Tm(2^(nd) heat)=127.2° C. GPC (135° C., TCB); Mn=1220, PDI=9.0. No branching was observed in the ¹³C-NMR analysis.

EXAMPLE 9

In a drybox under nitrogen, (XIV) (6.0 mg) was placed in a Schlenk flask and anhydrous toluene (5 ml) and 1-heptene (10 ml, distilled from Na) added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and PMAO-IP (0.9 ml) added. After 30 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=0.95 g white polymer. DSC (10° C./min., N₂); Tm(2^(nd) heat)=123.4° C., 110.6° C. GPC (135° C., trichlorobenzene); Mn=2540, PDI=5.3. ¹³C-NMR analysis indicated a total of 3.0 mol % 1-heptene incorporation. The observed number of short chain branches per 1000 CH₂ groups were methyl 0.7, and amyl 14.4.

COMPARATIVE EXAMPLE C

In a drybox under nitrogen, (XIV) (6.0 mg) was placed in a Schlenk flask and anhydrous toluene (15 ml) added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and PMAO-IP (0.9 ml) added. After 30 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. DSC (10° C./min., N₂); Tm(2^(nd) heat)=131.20° C. GPC (135° C., TCB); Mn=1410, PDI=20.0. No branching was observed in the ¹³C-NMR analysis.

EXAMPLE 10

In a drybox under nitrogen, (XIII) (6.1 mg) was placed in a Schlenk flask and anhydrous toluene (5 ml) and 1-pentene (10 ml, filtered through activated Al₂O₃ and stored over activated molecular sieves) added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and PMAO-IP (0.9 ml) added. After 30 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=0.82 g white polymer. DSC (10° C./min., N₂); Tm(2nd heat)=117.8° C., 90° C. (broad). GPC (135° C., TCB); Mn=1028, PDI=3.8. ¹³C-NMR analysis indicated a total of 10.0 mol % 1-pentene incorporation. The observed number of short chain branches per 1000 CH₂ groups were methyl 6.3, and propyl 50.9. GC analysis of the supernatant indicated negligible isomerization of the unreacted 1-pentene.

EXAMPLE 11

In a drybox under nitrogen, (XIII) (1.4 mg) was placed in ˜6 ml anhydrous toluene in a vial. 1-Pentene (30 ml, filtered through activated Al₂O₃ and stored over activated molecular sieves), anhydrous toluene (5 ml) and PMAO (0.5 ml, Akzo, 10.9 wt % Al in toluene) was placed in a Hoke cylinder and sealed. The containers were removed from the drybox. The 1-pentene slurry was placed in a 100 ml Parr® stirred autoclave. Ethylene (41 kPa) was added and stirring started. The catalyst solution was added to the reactor with an additional 10 psi ethylene. After 12 min the reaction was quenched by addition of MeOH. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=1.6 g white polymer. DSC (10° C./min., N₂); Tm(2^(nd) heat)=123.6° C. ¹³C-NMR analysis indicated a total of 0.8 mol % 1-pentene incorporation.

EXAMPLE 12

In a drybox under nitrogen, (XIII) (3.0 mg) was placed in a Schlenk flask and anhydrous toluene (5 ml) and 1-pentene (10 ml, filtered through activated Al₂O₃ and stored over activated molecular sieves) added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and MMAO-3A (0.45 ml, Akzo, 6.42 wt % Al in heptane) added. After 30 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=1.9 g white polymer. DSC (10° C./min., N₂); Tm(2^(nd) heat)=128.0° C. GPC (135° C., TCB); Mn=1716, PDI=7.0. ¹³C-NMR analysis (10 weight percent in TCB, 120° C.) indicated a total of 4.5 mol % 1-pentene incorporation. The observed number of short chain branches per 1000 CH₂ groups were methyl 2.4, propyl 21.7, and amyl 0.4. Any isopropyl or isobutyl end groups present due to initiator are not counted in the methyl group total. The observed NMR is given below together with the assignments. The assignments of A, B, C, D, E and F are shown in the structure below, with “P” representing the rest of the polymer chain.

and

Frequency PPM Height Assignment 3990.433 39.677 6.8 F 3950.917 39.284 7.1 C 3829.166 38.074 5.9 3792.320 37.708 53.3 MB₃₊ 3752.270 37.309 8.0 3696.200 36.752 58.8 3B₃ 3497.018 34.771 9.4 3451.628 34.320 105.7 αγ⁺B 3398.228 33.789 5.0 3293.031 32.743 7.2 2B₅, D 3222.543 32.042 21.0 3B₆₊, 3EOC 3139.773 31.219 6.5 3050.061 30.327 120.9 γγ⁺B 3002.535 29.855 2288.8 γ⁺γ⁺B 2960.883 29.440 56.7 2823.646 28.076 8.6 B 2763.838 27.481 12.4 2724.856 27.094 104.6 βγ⁺B 2442.904 24.290 2.4 2288.578 22.756 22.5 2B₅₊, 2EOC 2276.297 22.634 17.2 A 2029.055 20.175 63.0 2B₃ 1987.937 19.766 8.0 E 1459.812 14.515 60.5 1B₃ 1407.480 13.995 21.1 1B₄₊, 1EOC

EXAMPLE 13

In a drybox under nitrogen, (XIII) (3.0 mg) was placed in a Schlenk flask and anhydrous toluene (5 ml) and 1-pentene (10 ml, filtered through activated Al₂O₃ and stored over activated molecular sieves) added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and AlEt₃ (0.3 ml, 0.1M solution in toluene/hexane) and B(C₆F₅)₃ (0.0146 g in 0.5 ml toluene) were added. After 30 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=0.21 g white polymer. DSC (10° C./min., N₂); Tm(2^(nd) heat)=127.6° C. ¹³C-NMR analysis indicated a total of 0.64 mol % 1-pentene incorporation.

EXAMPLE 14

In a drybox under nitrogen, (XIII) (3.0 mg) was placed in a Schlenk flask and anhydrous toluene (5 ml) and 1-pentene (10 ml, filtered through activated Al₂O₃ and stored over activated molecular sieves) added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and IBAO-0.65 (0.45 ml, Akzo, 3.5 wt % Al in toluene) added. After 90 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. DSC (10° C./min., N₂); Tm(2^(nd) heat)=115.5° C. (bimodal). GPC (135° C., TCB); Mn=1957, PDI=8.9. ¹³C-NMR analysis (10 weight percent in TCB, 140° C.) indicated a total of 8.2 mol % 1-pentene incorporation. The observed number of short chain branches per 1000 CH₂ groups were methyl 3.4, and propyl 39.0. (amyl not integrated due to overlap). Any isopropyl or isobutyl end groups present due to initiator are not counted in the methyl group total. The assignments of A, B, C, D, E and F are shown in the structure below, with “P” representing the rest of the polymer chain.

and

Frequency PPM Height Assignment 3991.407 39.687 10.5 F 3951.357 39.289 8.9 C 3840.285 38.184 15.2 3802.371 37.807 179.7 MB₃₊ 3753.243 37.319 16.2 3706.251 36.852 200.4 3B₃ 3577.023 35.567 5.4 3509.740 34.898 27.2 3462.214 34.425 345.1 αγ⁺B 3391.192 33.719 7.8 3295.606 32.769 9.8 D 3271.576 32.530 8.2 3B₅ 3218.710 32.004 21.93 3B₆₊, 3EOC 3159.970 31.420 15.7 3084.142 30.666 35.7 3047.296 30.300 320.8 γγ⁺B 2998.168 29.811 3551.0 γ⁺γ⁺B 2954.915 29.381 64.8 2822.483 28.064 10.4 B 2777.093 27.613 16.5 2727.965 27.125 337.0 αγ⁺B 2565.629 25.510 3.9 2455.091 24.411 13.7 2282.076 22.691 24.5 2B₅₊, 2EOC 2270.862 22.579 23.9 A 2029.494 20.180 216.3 2B₃ 1986.774 19.755 13.3 E 1451.173 14.429 206.8 1B₃ 1397.239 13.893 24.1 1B₄₊, 1EOC 1355.054 13.473 6.7

Note: Existence of Me branches implies that these do not arise from the activator.

EXAMPLE 15

In a drybox under nitrogen, (XIII) (4.5 mg) was placed in a Schlenk flask and anhydrous toluene (5 ml) and 4-methyl-1-pentene (10 ml, filtered through activated Al₂O₃ and stored over activated molecular sieves) added. The flask was sealed and removed from the drybox. The flask was flushed with ethylene and PMAO-IP (0.9 ml) added. After 30 min the reaction was quenched by addition of MeOH/10% HCl. The solid polymer was filtered, washed well with MeOH/10% HCl, MeOH and finally acetone and dried under vacuum. Yield=4.65 g white polymer. DSC (10° C./min., N₂); Tm(2^(nd) heat)=121.4° C., 100.6° C. (broad). GPC (135° C., TCB); Mn 1740, PDI=5.0. ¹³C-NMR analysis indicated a total of 4.1 mol % 4-methyl-1-pentene incorporation.

EXAMPLE 16

In a dry box under nitrogen atmosphere, the iron complex 2,6-diacetylpyridinebis(2,4,6-trimethylphenylimine)iron dichloride (1.5 mg, 2.86 □mol) was weighed into a vial and diluted to 10 ml with toluene (Aldrich, Anhydrous 99.8%). An aliquot of 3 ml containing 0.45 mg (0.86 □mol) of catalyst was transferred to the injector vessel with 50 ml of toluene. To a second vessel, 100 ml of CaH₂ purified 1-octene (Aldrich, 98%) was mixed with 2 ml of MMAO-3A (Akzo Nobel). These solutions were transferred by pressure to a 600 ml Parr® autoclave reactor. The polymerization temperature was 120° C. and the ethylene pressure was 860 kPa, adjusted by a pressure regulator. The polymerization was run for 30 min. The reaction was quenched with methanol. The solid polymer was filtered and washed with acetone. Yield=2.68 g, DSC (10° C./min): Tm=126.2° C., HOF=212 J/g.

EXAMPLE 17

In a dry box under nitrogen atmosphere, an aliquot of 3 ml from the same stock solution of Example 16 was diluted with 50 ml of toluene and transferred to the injector vessel. To the second vessel, 80 ml of CaH₂ purified 1-octene (Aldrich, 98%) was mixed with 2 ml of MMAO-3A (Akzo Nobel). These solutions were transferred by pressure to a 600 Parr® autoclave reactor. The polymerization temperature was 60° C. and the ethylene pressure was 860 kPa, adjusted by a pressure regulator. The polymerization was run for 30 min. The reaction was quenched with methanol. The solid polymer was filtered, washed with acetone, and dried under vacuum. Yield=38.9 g, DSC (10° C./min): Tm=132.7° C., HOF=226 J/g.

EXAMPLE 18

In a dry box under nitrogen atmosphere, the iron complex [2,6-diacetylpyridinebis{(3,5-trifluoromethyl)phenylimine}] iron dichloride was weighed (6 mg, 9.7 □mol) and diluted to 100 ml of toluene (Aldrich, anhydrous, 99.8%) and spiked with 20 drops of methylene chloride (Aldrich). To this solution, 5.6 ml of MMAO-3A (Akzo Nobel) was added. This catalyst solution was transferred via cannula to a feed vessel of a catalyst pump. The pumping rate was constant for 15 min, resulting in 3.8 mg of catalyst used. For the comonomer, 85 ml of CaH₂ purified 1-hexene (Aldrich, 99%) was transferred to the reactor through a feed vessel. A 500 ml Zipperclave® reactor was charged with 165 ml of hexane (Aldrich, anhydrous, 95%+). The polymerization was run at 50° C. and 1.01 MPa of ethylene pressure. After 30 min, the reaction was quenched with methanol. The solid polymer was filtered, washed with acetone and dried under vacuum. Yield=1.4 g, DSC (10° C./min): Tm=126.6° C., with a shoulder at about 118° C. HOF=194 J/g. GPC Mw=11345, PDI=7.44.

COMPARATIVE EXAMPLE

Example 18 above was repeated with the same iron complex solution available in the catalyst pump feed vessel. No comonomer was added to this example. The catalyst pumping rate was constant for the first 15 min of the run, resulting in 2.3 mg of catalyst used. A 500 ml Zipperclave® reactor was charged with 250 ml of hexane (Aldrich, anhydrous, 95%). The polymerization was run at 50° C. and 1.01 MPa of ethylene pressure. After 30 min, the reaction was quenched with methanol. The solid polymer was filtered, washed with acetone and dried under vacuum. Yield=3.4 g, DSC (1° C./min): Tm=130.3° C., HOF=278 J/g. Mw=14434, PDI=6.03 

1-22. (canceled)
 23. A copolymer of ethylene and a one or more olefins of the formula H₂C═CHR²¹ wherein R²¹ is alkyl other than methyl, and said copolymer has methyl branches and —R²¹ branches, and wherein the total of said branches indicate an incorporation of H₂C═CHR²¹ of at least 0.5 mole percent.
 24. The copolymer as recited in claim 23 wherein said incorporation is at least 1 mole percent.
 25. The copolymer as recited in claim 23 or 24 wherein each of said methyl branches is attached to a carbon atom, and an —R²¹ group is also attached to said carbon atom.
 26. The copolymer as recited in claim 23 or 24 wherein R²¹ is n-alkyl.
 27. The copolymer as recited in claim 25 wherein R²¹ is n-alkyl.
 28. (canceled)
 29. The copolymer as recited in claim 23 wherein R²¹ is n-alkyl containing 2 to 8 carbon atoms. 